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Modification of Styrofoam Waste as a Low-Cost Adsorbent for Removal of Cadmium Ion in Aqueous Solution

Ismi M. N. Milla , Mia A. Syahri , Endang T. Wahyuni* , Roto Roto and Dwi Siswanta

1Department of Chemistry, Faculty of Mathematics and Natural Sciences Universitas Gadjah Mada, Sekip Utara PO Box Bls 21 Yogyakarta, 55284 Indonesia .

Corresponding author Email: endang_triw@ugm.ac.id

DOI: http://dx.doi.org/10.13005/OJPS03.02.08

waste has been modified by sulfonation using sulfuric acid to form its corresponding sulfonated adsorbent and was further used for removing cadmium ion in its  aqueous solution.  The effect of the styrofoam weight, sulfuric acid concentration, temperature and time on the sulfonation result was evaluated.  The prepared adsorbent was characterized by XRD, FTIR, and SEM.  The cadmium ion adsorption was conducted by batch technique, where the kinetic parameters were determined.  The research results attribute that  the sulfonated  styrofoam has been successfully prepared, and the highest sulfonation is exhibited by  using 18M of the  sulfuric acid, at 60 oC for 6 h with 5 g of styrofoam. The cadmium adsorption by the sulfonated styrofoam fits with the pseudo-second-order and the Langmuir isotherm model, while the native styrofoam follows the intraparticle diffusion mechanism and Freundlich isotherm model. The adsorption capacities of the sulfonated and   the native styrofoam are 51.6 mg/g and 7.09 mg/g  respectively,  and their respective adsorption rate are 8.20 10-3 mg. g-1. min-1  and 26.9 10-3 mg.g-1 min-1/2 .


Adsorption; Styrofoam; Sulfonation; Toxic Cd Ions

Copy the following to cite this article:

Milla I. M. N, Syahri M. A, Wahyuni E. T, Roto R, Siswanta D. Orient J Phys Sciences 2018;3(2).

DOI:http://dx.doi.org/10.13005/OJPS03.02.08

Copy the following to cite this URL:

Milla I. M. N, Syahri M. A, Wahyuni E. T, Roto R, Siswanta D. Orient J Phys Sciences 2018;3(2). Available from: https://bit.ly/3jmj8GK


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